CNS
Meeting
Monday Mar 22, 11:00 AM, W505 Howey
Normal-form calculation of molecular tunneling paths
Thomas Bartsch
Quantum-mechanical tunneling rates are determined, in the semiclassical
approximation, by the action integral along a complex classical trajectory
below the barrier. In asymmetric multidimensional potentials, the most
efficient tunneling path can deviate markedly from the steepest-descent
path down from the barrier. Normal-form theory allows to construct a
coordinate transformation that brings the barrier into a symmetric shape and
thus permits an easy identification of the tunneling path. I will
illustrate this method by constructing tunneling paths for the hydrogen
molecular ion in an electric field.